Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: Delta(3)-carene, isoprene, methacrolein and methyl vinyl ketone
The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 +/- 0.8) x 10(-10), (2.1 +/- 0.5) x 10(-10), (3.2 +/- 0.5) x 10(-10), and (4.9 +/- 0.5) x 10(-10) cm(3) molecule(-1) s(-1), for reactions with isoprene, methyl vinyl ketone, methacrolein and Delta(3)-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.
%0 Generic
%1 CanosaMas:1999p3131
%A Canosa-Mas, CE
%A Hutton-Squire, HR
%A King, MD
%A Stewart, DJ
%A Thompson, KC
%A Wayne, RP
%D 1999
%J Journal of Atmospheric Chemistry
%K 298 Alkanes, And Atoms, Chlorine Chlorine, Constants, Delta(3)-Carene, Hydrocarbons, Isoprene, K Ketone, Kinetics, Methacrolein Methyl Oh, Rate Vinyl
%N 1
%P 163--170
%T Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: Delta(3)-carene, isoprene, methacrolein and methyl vinyl ketone
%U http://www.google.com/search?client=safari&rls=en-us&q=Laboratory+kinetic+studies+of+the+reactions+of+Cl+atoms+with+species+of+biogenic+origin:+Delta(3)-carene,+isoprene,+methacrolein+and+methyl+vinyl+ketone&ie=UTF-8&oe=UTF-8
%V 34
%X The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 +/- 0.8) x 10(-10), (2.1 +/- 0.5) x 10(-10), (3.2 +/- 0.5) x 10(-10), and (4.9 +/- 0.5) x 10(-10) cm(3) molecule(-1) s(-1), for reactions with isoprene, methyl vinyl ketone, methacrolein and Delta(3)-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.
@proceedingspaper{CanosaMas:1999p3131,
abstract = {The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 +/- 0.8) x 10(-10), (2.1 +/- 0.5) x 10(-10), (3.2 +/- 0.5) x 10(-10), and (4.9 +/- 0.5) x 10(-10) cm(3) molecule(-1) s(-1), for reactions with isoprene, methyl vinyl ketone, methacrolein and Delta(3)-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.},
added-at = {2010-06-22T19:38:37.000+0200},
affiliation = {Univ Oxford, Phys {\&} Theoret Chem Lab, Oxford OX1 3QZ, England},
author = {Canosa-Mas, CE and Hutton-Squire, HR and King, MD and Stewart, DJ and Thompson, KC and Wayne, RP},
biburl = {https://www.bibsonomy.org/bibtex/2f7fe16d52af885506aa4f20bc183ade1/gsmith},
date-added = {2010-04-28 10:58:46 -0400},
date-modified = {2010-04-28 10:58:51 -0400},
interhash = {90f386f0e827424c385190f26b6aadd6},
intrahash = {f7fe16d52af885506aa4f20bc183ade1},
journal = {Journal of Atmospheric Chemistry},
keywords = {298 Alkanes, And Atoms, Chlorine Chlorine, Constants, Delta(3)-Carene, Hydrocarbons, Isoprene, K Ketone, Kinetics, Methacrolein Methyl Oh, Rate Vinyl},
language = {English},
local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Journal%20of%20Atmospheric%20Chemistry/1999/Journal%20of%20Atmospheric%20Chemistry,%2034,%20163-170%201999.pdf},
month = Jan,
number = 1,
pages = {163--170},
pmid = {000082797800012},
rating = {0},
timestamp = {2010-06-22T19:39:25.000+0200},
title = {Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: Delta(3)-carene, isoprene, methacrolein and methyl vinyl ketone},
uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3131},
url = {http://www.google.com/search?client=safari&rls=en-us&q=Laboratory+kinetic+studies+of+the+reactions+of+Cl+atoms+with+species+of+biogenic+origin:+Delta(3)-carene,+isoprene,+methacrolein+and+methyl+vinyl+ketone&ie=UTF-8&oe=UTF-8},
volume = 34,
year = 1999
}