Self-assembly versus complexation with polycyclic aromatic hydrocarbon (PAH) guest molecules is studied for a series of perylene bisimides (PBIs). Bulky imide substituents at the PBI guide their self-assembly into dimer aggregates with null-type exciton coupling. Host–guest titration experiments with perylene and triphenylene PAHs afford 1 : 1 and 1 : 2 complexes whose properties are studied by single crystal X-ray analysis and UV/Vis and fluorescence spectroscopy.
%0 Journal Article
%1 D3CC03704E
%A Soldner, Simon
%A Anhalt, Olga
%A Sárosi, Menyhárt B.
%A Stolte, Matthias
%A Würthner, Frank
%D 2023
%J Chem. Commun.
%K myown
%N 78
%P 11656-11659
%R 10.1039/D3CC03704E
%T Donor–acceptor complex formation by social self-sorting of polycyclic aromatic hydrocarbons and perylene bisimides
%U http://dx.doi.org/10.1039/D3CC03704E
%V 59
%X Self-assembly versus complexation with polycyclic aromatic hydrocarbon (PAH) guest molecules is studied for a series of perylene bisimides (PBIs). Bulky imide substituents at the PBI guide their self-assembly into dimer aggregates with null-type exciton coupling. Host–guest titration experiments with perylene and triphenylene PAHs afford 1 : 1 and 1 : 2 complexes whose properties are studied by single crystal X-ray analysis and UV/Vis and fluorescence spectroscopy.
@article{D3CC03704E,
abstract = {Self-assembly versus complexation with polycyclic aromatic hydrocarbon (PAH) guest molecules is studied for a series of perylene bisimides (PBIs). Bulky imide substituents at the PBI guide their self-assembly into dimer aggregates with null-type exciton coupling. Host–guest titration experiments with perylene and triphenylene PAHs afford 1 : 1 and 1 : 2 complexes whose properties are studied by single crystal X-ray analysis and UV/Vis and fluorescence spectroscopy.},
added-at = {2023-09-29T11:13:43.000+0200},
author = {Soldner, Simon and Anhalt, Olga and Sárosi, Menyhárt B. and Stolte, Matthias and Würthner, Frank},
biburl = {https://www.bibsonomy.org/bibtex/2749b473109b74baf4d25c4b2155def52/wuerthner_group},
doi = {10.1039/D3CC03704E},
interhash = {57924783d15c9270cb1c94cdfe221bf8},
intrahash = {749b473109b74baf4d25c4b2155def52},
journal = {Chem. Commun.},
keywords = {myown},
number = 78,
pages = {11656-11659},
timestamp = {2024-01-25T14:36:35.000+0100},
title = {Donor–acceptor complex formation by social self-sorting of polycyclic aromatic hydrocarbons and perylene bisimides},
url = {http://dx.doi.org/10.1039/D3CC03704E},
volume = 59,
year = 2023
}